Harvest EasyGum Bond - Safety Data Sheet

Created by Ceci Alvarado, Modified on Fri, 20 Sep at 4:41 PM by Ceci Alvarado


                                                                                                            Date Prepared: 9.17.2024 

                                                                                                                                     SDS No.: EasyGum Bond 

                                                                                                                                      Revision No.: 2


1. PRODUCT AND COMPANY IDENTIFICATION 


PRODUCT DESCRIPTION: EasyGum Bond            USE OR APPLICATION: Light Cure Composite Adhesive 


Company Information:                                             USA    

Company Name:                                                         Harvest Dental Products, LLC    

Street: City/ Zip: State/ Province:                                905 Columbia St. Brea, 92821 California    

Country:                                                                      USA    

Telephone:                                                                  1+714-674-7400    

Emergency Telephone:                                               Infotrac: 1+800-535-5053


2. HAZARDS IDENTIFICATION


        Hazzard Classification: 

    

Flammable liquids Category 2  
Skin corrosion/irritation Category 2 
Serious eye damage/eye irritation Category 2
Skin sensitization, Category 1  
Reproductive toxicity Category 1B  
  Highly flammable liquid and vapor  
Causes skin irritation  
Causes serious eye irritation  
  May cause an allergic skin reaction  
May damage fertility or the unborn child 


        GHS US Labeling


 Hazard Pictograms (GHS US): 
Signal Ward (GHS US): Danger
Hazard Statements: Highly flammable liquid and vapor 
Causes skin irritation  
   May cause an allergic skin reaction  
    Causes serious eye irritation  
    May damage fertility or the unborn child
Precautionary Statements (GHS US): 

Obtain special instructions before use. 

Do not handle until all safety precautions have been read and understood.  
    Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.  
    Keep container tightly closed. 
    Use explosion-proof electrical/ventilating/lighting     equipment  
    Use only non-sparking tools.  
   Avoid breathing vapors, spray. 

 Wash hands thoroughly after handling.  
   Contaminated work clothing must not be allowed     out of the workplace 
    Wear protective gloves, eye protection.  

    If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with     water/shower 
    If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 
    If exposed or concerned: Get medical advice/attention. 
   If skin irritation or rash occurs: Get medical advice/attention.  
    If eye irritation persists: Get medical advice/attention. 
    Take off contaminated clothing and wash it before reuse.  
    Wash contaminated clothing before reuse. 
  Store in a well-ventilated place. Keep cool.   

   Store locked up. 
    Dispose of contents/container to hazardous or     special waste collection point, in accordance with     local, regional, national and/or international     regulation


        

Other Unclassified Hazards 
No additional information available 

Unknown Acute Toxicity (GHS US) 
Not applicable

 3. COMPOSITION / INFORMATION ON INGREDIENTS 

    

        Substances: 

            Not applicable

    

        Mixtures


NameCAS NoPercentageGHS-US Classification 
2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester  
(CAS-No.) 1565-94-2   15 - 40  

Skin Irrit. 2, H315  

Eye Irrit. 2A, H319  

Skin Sens. 1, H317 

Ethyl alcoho(CAS-No.) 64-17-5  
15 – 40   

Flam. Liq. 2, H225  

Eye Irrit. 2A, H319  

Bis[2-[(2-methyl-1-oxoallyl)oxy]ethyl] dihydrogen benzene-1,2,4,5-tetracarboxylate   

(CAS-No.) 51156-91-3  
10 - 30  

Skin Irrit. 2, H315  

Eye Irrit. 2A, H319  

STOT SE 3, H335  

Comb. Dust  

2-hydroxyethyl methacrylate  (CAS-No.) 868-77-9  10 - 30   

Skin Irrit. 2, H315  

Eye Irrit. 2, H319  

Skin Sens. 1, H317  

10- Methacryloyloxydecyl dihydrogen phosphate (10-MDP)   (CAS-No.) 85590-00-7   7 - 13   

Eye Irrit. 2, H319  

Skin Sens. 1, H317  

Acetone   (CAS-No.) 67-64-1   1 - 5   

Flam. Liq. 2, H225  

Eye Irrit. 2, H319  

STOT SE 3, H336   

Benzoic acid, 4-(dimethylamino)-, ethyl ester  (CAS-No.) 10287-53-3  0.5 – 1.5Repr. 1B, H360

 

4. FIRST AID MEASURES


Description of first aid measures 


First-aid measures after inhalation: Remove person to fresh air and keep comfortable for breathing.  
    Give artificial respiration if necessary. If you feel unwell, seek medical advice.  
First-aid measures after skin contact:Immediately, remove all contaminated clothing. Rinse immediately with plenty of water for 15 minutes. Seek medical advice if skin irritation persists
First-aid measures after eye contact:Remove contact lenses, if present and easy to do.Continue rinsing.  
    Rinse immediately with plenty of water for 15 minutes.   
    If eye irritation persists: Seek medical advice and attention. 
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention


Most important symptoms and effects, both acute and delayed 

Symptoms/effects:   
Symptoms/effects after inhalation: 

Symptoms/effects after skin contact: 
Symptoms/effects after eye contact: 
Symptoms/effects after ingestion: 
  May damage fertility or the unborn child.  
Not expected to present a significant inhalation hazard under anticipated conditions of normal use.  
  Causes skin irritation. May cause an allergic skin reaction.  

Causes serious eye irritation.  
May cause irritation to the digestive tract. 


Indication of any immediate medical attention and special treatment, if needed 

Treat symptomatically. 

5. FIRE FIGHTING MEASURE


Suitable & Unsuitable Extinguishing media  

Suitable Extinguishing media:  Water spray, Foam, dry powder, carbon dioxide. Sand.
Unsuitable Extinguishing media:Do not use a heavy water stream 


Special hazards arising from the substance or mixture  


Fire hazard: On combustion, forms: carbon oxides (CO and CO2).
Explosion hazard:   May form flammable vapor-air mixture. Vapors may travel long distances along the ground before igniting/flashing back to vapor source.   
Reactivity in case of fire: Stable under normal conditions.


Advice for firefighters  


Firefighting instructions:  Use water spray or fog for cooling exposed containers.  
Exercise caution when fighting any chemical fire. Prevent 
firefighting water from entering the environment.  

Protective equipment for firefighters:
Do not enter fire area without proper protective equipment,     including respiratory protection. 
Protective equipment for firefighters:  Do not enter fire area without proper protective equipment, including respiratory protection

                         

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment, and emergency procedures  

General measures: Keep away from open flames, hot surfaces, and sources of ignition.

                          


For non-emergency personnel  


Protective equipment:   Use personal protective equipment as required. For further  information refer to section 8: "Exposure controls/personal protection"
 Emergency procedures: 
Evacuate unnecessary personnel. 


For emergency responders  

Protective equipment:
Wear recommended personal protective equipment. For further information refer to Section 8: "Exposure controls/personal protection".
Emergency procedures:
Ventilate area.


Environmental precautions  


Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.  


Methods and material for containment and cleaning up  


Methods for cleaning up: 
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials
Other information: 
Dispose of materials or solid residues at an authorized site

 

Reference to other sections  
            

For further information refer to section 8: "Exposure controls/personal protection". For disposal of residues refer to section 13: "Disposal considerations". 


7. HANDLING AND STORAGE


Precautions for safe handling  


Additional hazards when processed:
 Handle empty containers with care as residual vapors are flammable.
Precautions for safe handling:
Ensure good ventilation of the workstation. Avoid contact with eyes. Wear personal protective equipment. Avoid breathing vapors, mist.
Hygiene measures: Do not eat, drink, or smoke when using this product. Always wash hands after handling the product. Wash contaminated clothing before reuse. Handle in accordance with good industrial hygiene and safety practice.


Conditions for safe storage, including any incompatibilities  


Technical measures: Use explosion-proof electrical/ventilating/lighting equipment. Keep away from open flames, hot surfaces, and sources of ignition. 
Storage conditions: Store in a well-ventilated place. Keep cool. 
Incompatible materials: None known. 


Specific end use(s)  
    See Section 1. 


8. EXPOSURE CONTROLS / PERSONAL PROTECTION 


Control Parameters:  

Ingredients 

 

Value 

Bis[2-[(2-methyl-1-oxoallyl)oxy]ethyl] dihydrogen benzene-1,2,4,5-tetracarboxylate 

Not applicable 

 

Acetone 

Local Name 

Acetone  

ACGIH TWA  

250 ppm 

ACGIH STEL 

500 ppm 

ACGIH Remark 

TLV® Basis: URT & eye irr; CNS impair. Notations: A4 (Not classifiable as a Human Carcinogen); BEI 

BEI 

25 mg/l Parameter: Acetone - Medium: urine - Sampling time: End of shift - Notations: Ns 

Regulatory Reference 

ACGIH 2019 

OSHA PEL (TWA) 

2400 mg/m³ 

OSHA PEL (TWA) 

1000 ppm 

Regulatory reference 

OSHA Annotated Table Z-1 

NIOSH REL (TWA) 

590 mg/m³ 

NIOSH REL (TWA) 

250 ppm 

2-hydroxyethyl methacrylate 

Not applicable 

 

2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1- phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester 

Not applicable 

 

10- Methacryloyloxydecyl dihydrogen phosphate (10-MDP) 

Not applicable 

 

Ethyl alcohol 

Local Name 

Ethanol 

ACGIH STEL 

1000 ppm 

ACGIH Remark 

TLV® Basis: URT irr. Notations: A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans) 

Regulatory Reference 

ACGIH 2019 

OSHA PEL (TWA) 

1900 mg/m³ 

OSHA PEL (TWA) 

1000 ppm 

Regulatory reference 

OSHA Annotated Table Z-1 

US IDLH 

3300 ppm (10% LEL) 

NIOSH REL (TWA) 

1900 mg/m³ 

NIOSH REL (TWA) 

1000 ppm 

Benzoic acid, 4-(dimethylamino)-, ethyl ester 

Not applicable 

 


Appropriate Engineering Controls 

Appropriate Engineering: Ensure good ventilation of the workstation. Emergency eye-wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. 
Environmental Exposure Controls: Avoid release to the environment. 


Individual Protection Measures/Personal Protective Equipment 

Hand protection:  
Impermeable protective gloves.  

Eye protection:  
Safety glasses with side shields.  

Skin and body protection:  
Long sleeved protective clothing  

Respiratory protection:  
In case of inadequate ventilation wear respiratory protection.  

Other information:  
Do not eat, drink or smoke during use  


9. PHYSICAL AND CHEMICAL PROPERTIES 


Information on basic physical and chemical properties 
Physical state:     Liquid  
Appearance:     Liquid 
Color:     Pale yellow.  
Odor:     Ethanol  
Odor threshold:     No data available  
pH:     No data available  
Melting point:     < 0 °C  
Freezing point:     No data available  
Boiling point:     > 50 °C  
Flash point:     No data available 
Relative evaporation rate (butylacetate=1):     No data available 
Flammability (solid, gas):     Not applicable  
Vapor pressure:     No data available 
Relative vapor density at 20 °C:     No data available 
Relative density:     No data available 
Solubility:    No data available 
Log Pow:    No data available 
Auto-ignition temperature:     No data available  
Decomposition temperature:     No data available  
Viscosity, kinematic:    No data available  
Viscosity, dynamic:     No data available  
Explosive limits:     No data available 
Explosive properties:     No data available  
Oxidizing properties:     No data available  

Other Information  
No additional information available 

10. STABILITY AND REACTIVITY  

Reactivity  
No dangerous reactions known under normal conditions of use.  

Chemical stability  
Stable at ambient temperature and under normal conditions of use.  

Possibility of hazardous reactions  
No dangerous reactions known under normal conditions of use.  

Conditions to avoid  
None known.  

Incompatible materials  
None known.  

Hazardous decomposition products  
No hazardous decomposition products known at room temperature. On combustion, forms: carbon oxides (CO and CO2) 


11. TOXICOLOGICAL INFORMATION 


Information on toxicological effects  
Acute toxicity (oral):     Not classified (Based on available data, the classification criteria are not met)  
Acute toxicity (dermal):     Not classified (Based on available data, the classification criteria are not met)  
Acute toxicity (inhalation):     Not classified (Based on available data, the classification criteria are not met)  

Acetone (67-64-1)  

LD50 oral rat  5800 mg/kg  
LD50 dermal rabbit 15700 mg/kg  
LC50 inhalation rat (mg/l)   50100 mg/m³ (Exposure time: 8 h) 


Ethyl alcohol (64-17-5)  

LD50 oral rat  7060mg/kg
LC50 inhalation rat (mg/l)    124.7 mg/l/4h 

 

General: 

Skin corrosion/irritation:  Causes skin irritation. 
Serious eye damage/irritation:  Causes serious eye irritation. 
Respiratory or skin sensitization May cause an allergic skin reaction. 
Germ cell mutagenicity:  
Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity: Not classified (Based on available data, the classification criteria are not met)
Reproductive toxicity: May damage fertility or the unborn child. 
Aspiration hazard: Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity – repeated exposure: Not classified (Based on available data, the classification criteria are not met) 
Aspiration hazard: Not classified (Based on available data, the classification criteria are not met)
Viscosity, kinematic: No data available 
Symptoms/effects:  May damage fertility or the unborn child. 
Symptoms/effects after inhalation:
Not expected to present a significant inhalation hazard under anticipated conditions of normal use. 
Symptoms/effects after skin contact: Causes skin irritation. May cause an allergic skin reaction 
Symptoms/effects after eye contact: Causes serious eye irritation. 
Symptoms/effects after ingestion: May cause irritation to the digestive tract. 
Other information: Likely routes of exposure: ingestion, inhalation, skin, and eye. 

12. ECOLOGICAL INFORMATION


Toxicity  
Ecology - general:     This material has not been tested for environmental effects.  
Acute aquatic toxicity:     Not classified (Based on available data, the classification criteria are not met)  
Chronic aquatic toxicity:     Not classified (Based on available data, the classification criteria are not met)  

Acetone (67-64-1)  

LC50 fish 1  4.74 - 6.33 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) 
LC50 fish 2  6210 - 8120 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 
EC50 Daphnia 1 10294 - 17704 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 
EC50 Daphnia 2 12600 - 12700 mg/l (Exposure time: 48 h - Species: Daphnia magna) 
ErC50 (algae) 2800 mg/l 14days

 

Ethyl alcohol (64-17-5)  

LC50 fish 1  12.0 - 16.0 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) 
LC50 fish 2  100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])  
LC50 other aquatic organisms  1 5012 mg/l 48 hours- daphnia  
EC50 Daphnia 1   9268 - 14221 mg/l (Exposure time: 48 h - Species: Daphnia magna) 
EC50 Daphnia 2  2 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])  
ErC50 (algae)  275 mg/l ErC50 (other aquatic plants) 4432 mg/l 
NOEC (acute)    9.6 mg/l Daphnia magna 

 

Persistence and degradability  
No additional information available  

Bioaccumulative potential  

Acetone (67-64-1)  
BCF fish 1                             0.69  
Log Pow                                  -0.24  

Ethyl alcohol (64-17-5)  
Log Pow      -0.32  

Mobility in soil  
No additional information available  

Other adverse effects Additional information:  
Avoid release to the environment 


13. DISPOSAL CONSIDERATIONS 


13.1. Waste treatment methods  
Product/Packaging disposal recommendations:    Dispose in a safe manner in accordance with local/national regulations.  
Ecology - waste materials:     Avoid release to the environment.  


14. TRANSPORT INFORMATION 


In accordance with: ADR / RID / IMDG / IATA / AND 

Overland Transportation 

Classification code (ADR): F1 
Special provisions (ADR): 274, 601, 640D 
Limited quantities (ADR): 1l 
Excepted quantities (ADR): E2 
Packing instructions (ADR): P001, IBC02, R001
Mixed packing provisions (ADR): MP19 
Portable tank and bulk container instructions (ADR): T7
Portable tank and bulk container special provisions (ADR): TP1, TP8, TP28 
Tank code (ADR): LGBF 
Vehicle for tank carriage:
FL
Transport category (ADR): 2
Special provisions for carriage - Operation (ADR): S2, S20 
Hazard identification number (Kemler No.): 33
Orange Plates: 
Tunnel restriction code (ADR): D/E 
EAC code: •3YE


Transportation By Sea

Excepted quantities (IMDG): E2


Air Transportation 

Excepted quantities (IATA): E2


Inland Waterway Transportation

Classification code (ADN) F1
Special provisions (ADN):
274, 601, 640D
Limited quantities (ADN):
1 L
Excepted quantities (ADN): E2
Carriage permitted (ADN):
T
Equipment required (ADN):
PP, EX, A
Ventilation (ADN):
VE01
Number of blue cones/lights (ADN): 1


Rail Transportation 


Classification code (RID): F1
Special provisions (RID):
274, 601, 640D
Limited quantities (RID):
1 L
Excepted quantities (RID):
E2
Packing instructions (RID):
P001, IBC02, R001
Mixed packing provisions (RID): MP19
Portable tank and bulk container instructions (RID):
T7
Portable tank and bulk container special provisions (RID): 
TP1, TP8, TP28
Tank codes for RID tanks (RID):
LGBF
Transport category (RID):
2
Colis express (express parcels) (RID):
CE7


15. REGULATORY INFORMATION 


US Federal Regulations 

Acetone (67-64-1)  
 Listed on the United States TSCA (Toxic Substances Control Act) inventory 
CERCLA RQ:    5000lbs 

2-hydroxyethyl methacrylate (868-77-9) 
Listed on the United States TSCA (Toxic Substances Control Act) inventory 

2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester (1565-94-2) 
Listed on the United States TSCA (Toxic Substances Control Act) inventory 

Ethyl alcohol (64-17-5) 
Listed on the United States TSCA (Toxic Substances Control Act) inventory 

Benzoic acid, 4-(dimethylamino)-, ethyl ester (10287-53-3) 
Listed on the United States TSCA (Toxic Substances Control Act) inventory 


16. OTHER INFORMATION 

What is the NFPA?







PREPARED BY: Jörg Erxleben 

REVISION SUMMARY: First Edition. 

MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, Harvest Dental Products, LLC does not assume any liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. 

 


FRM-SDS-21 REV 02 

Updated to Knowledge Base: September 20, 2024

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