SAFETY DATA SHEET Date Prepared: 5.22.2024
SDS No.: EasyGum Bond
Revision No.: 1
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT DESCRIPTION: EasyGum Bond USE OR APPLICATION: Light Cure Composite Adhesive
Company Information: USA
Company Name: Harvest Dental Products, LLC
Street: City/ Zip: State/ Province: 905 Columbia St. Brea, 92821 California
Country: USA
Telephone: 1+714-674-7400
Emergency Telephone: Infotrac: 1+800-535-5053
2. HAZARDS IDENTIFICATION
Hazzard Classification:
| Flammable liquids Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization, Category 1 Reproductive toxicity Category 1B | Highly flammable liquid and vapor Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May damage fertility or the unborn child |
GHS US Labeling
Hazard Pictograms (GHS US):
Signal Ward (GHS US): Danger
Hazard Statements:
Highly flammable liquid and vapor
Causes skin irritation
May cause an allergic skin reaction
Causes serious eye irritation
May damage fertility or the unborn child
Precautionary Statements (GHS US):
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower |
Other Unclassified Hazards
No additional information available
Unknown Acute Toxicity (GHS US)
Not applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Substances:
Not applicable
Mixtures
| Name | CAS No | Percentage | GHS-US Classification |
| 2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester | (CAS-No.) 1565-94-2 | 15 - 40 | Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Skin Sens. 1, H317 |
| Ethyl alcohol | (CAS-No.) 64-17-5 | 15 – 40 | Flam. Liq. 2, H225 Eye Irrit. 2A, H319 |
Bis[2-[(2-methyl-1-oxoallyl)oxy]ethyl] dihydrogen benzene-1,2,4,5-tetracarboxylate | (CAS-No.) 51156-91-3 | 10 - 30 | Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 Comb. Dust |
| 2-hydroxyethyl methacrylate | CAS-No.) 868-77-9 | 10 - 30 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| 10- Methacryloyloxydecyl dihydrogen phosphate (10-MDP) | (CAS-No.) 85590-00-7 | 7 - 13 | Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Acetone | (CAS-No.) 67-64-1 | 1 - 5 | Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 |
| Benzoic acid, 4-(dimethylamino)-, ethyl ester | (CAS-No.) 10287-53-3 | 0.5 – 1.5 | Repr. 1B, H360 |
4. FIRST AID MEASURES
Description of first aid measures
| First-aid measures after inhalation: | Remove person to fresh air and keep comfortable for breathing. Give artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact: | Immediately, remove all contaminated clothing. Rinse immediately with plenty of water for 15 minutes. Seek medical advice if skin irritation persists |
| First-aid measures after eye contact: | Remove contact lenses, if present and easy to do.Continue rinsing. Rinse immediately with plenty of water for 15 minutes. If eye irritation persists: Seek medical advice and attention. |
| First-aid measures after ingestion: | Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention |
Most important symptoms and effects, both acute and delayed
| Symptoms/effects: Symptoms/effects after inhalation: Symptoms/effects after skin contact: Symptoms/effects after eye contact: Symptoms/effects after ingestion: | May damage fertility or the unborn child. Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause irritation to the digestive tract. |
Indication of any immediate medical attention and special treatment, if needed
Treat symptomatically.
5. FIRE FIGHTING MEASURE
Suitable & Unsuitable Extinguishing media
Suitable Extinguishing media: Water spray, Foam, dry powder, carbon dioxide. Sand.
Unsuitable Extinguishing media: Do not use a heavy water stream
Special hazards arising from the substance or mixture
Fire hazard: On combustion, forms: carbon oxides (CO and CO2).
Explosion hazard: May form flammable vapor-air mixture. Vapors may travel
long distances along ground before igniting/flashing back to
vapor source.
Reactivity in case of fire: Stable under normal conditions.
Advice for firefighters
Firefighting instructions: Use water spray or fog for cooling exposed containers.
Exercise caution when fighting any chemical fire. Prevent
firefighting water from entering the environment.
Protective equipment for firefighters: Do not enter fire area without proper protective equipment,
including respiratory protection.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures
General measures: Keep away from open flames, hot surfaces, and sources of
ignition.
For non-emergency personnel
Protective equipment: Use personal protective equipment as required. For further
information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures: Evacuate unnecessary personnel.
For emergency responders
Protective equipment: Wear recommended personal protective equipment. For further
information refer to Section 8: "Exposure controls/personal
protection".
Emergency procedures: Ventilate area.
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
Methods and material for containment and cleaning up
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Collect spillage. Store away from other
materials.
Other information: Dispose of materials or solid residues at an authorized site.
Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection". For disposal of residues refer to section 13: "Disposal considerations".
7. HANDLING AND STORAGE
Precautions for safe handling
Additional hazards when processed: Handle empty containers with care as residual vapors are
flammable.
Precautions for safe handling: Ensure good ventilation of the workstation. Avoid contact with
eyes. Wear personal protective equipment. Avoid breathing
vapors, mist.
Hygiene measures: Do not eat, drink, or smoke when using this product. Always wash
hands after handling the product. Wash contaminated clothing
before reuse. Handle in accordance with good industrial hygiene
and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures: Use explosion-proof electrical/ventilating/lighting equipment.
Keep away from open flames, hot surfaces, and sources of
ignition.
Storage conditions: Store in a well-ventilated place. Keep cool.
Incompatible materials: None known.
Specific end use(s)
See Section 1.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters:
Ingredients |
| Value |
Bis[2-[(2-methyl-1-oxoallyl)oxy]ethyl] dihydrogen benzene-1,2,4,5-tetracarboxylate | Not applicable |
|
Acetone | Local Name | Acetone |
ACGIH TWA | 250 ppm | |
ACGIH STEL | 500 ppm | |
ACGIH Remark | TLV® Basis: URT & eye irr; CNS impair. Notations: A4 (Not classifiable as a Human Carcinogen); BEI | |
BEI | 25 mg/l Parameter: Acetone - Medium: urine - Sampling time: End of shift - Notations: Ns | |
Regulatory Reference | ACGIH 2019 | |
OSHA PEL (TWA) | 2400 mg/m³ | |
OSHA PEL (TWA) | 1000 ppm | |
Regulatory reference | OSHA Annotated Table Z-1 | |
NIOSH REL (TWA) | 590 mg/m³ | |
NIOSH REL (TWA) | 250 ppm | |
2-hydroxyethyl methacrylate | Not applicable |
|
2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1- phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester | Not applicable |
|
10- Methacryloyloxydecyl dihydrogen phosphate (10-MDP) | Not applicable |
|
Ethyl alcohol | Local Name | Ethanol |
ACGIH STEL | 1000 ppm | |
ACGIH Remark | TLV® Basis: URT irr. Notations: A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans) | |
Regulatory Reference | ACGIH 2019 | |
OSHA PEL (TWA) | 1900 mg/m³ | |
OSHA PEL (TWA) | 1000 ppm | |
Regulatory reference | OSHA Annotated Table Z-1 | |
US IDLH | 3300 ppm (10% LEL) | |
NIOSH REL (TWA) | 1900 mg/m³ | |
NIOSH REL (TWA) | 1000 ppm | |
Benzoic acid, 4-(dimethylamino)-, ethyl ester | Not applicable |
|
Appropriate Engineering Controls
Appropriate Engineering: Ensure good ventilation of the workstation. Emergency
eye-wash fountains and safety showers should be
available in the immediate vicinity of any potential
exposure.
Environmental Exposure Controls: Avoid release to the environment.
Individual Protection Measures/Personal Protective Equipment
Hand protection:
Impermeable protective gloves.
Eye protection:
Safety glasses with side shields.
Skin and body protection:
Long sleeved protective clothing
Respiratory protection:
In case of inadequate ventilation wear respiratory protection.
Other information:
Do not eat, drink or smoke during use
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state: Liquid
Appearance: Liquid
Color: Pale yellow.
Odor: Ethanol
Odor threshold: No data available
pH: No data available
Melting point: < 0 °C
Freezing point: No data available
Boiling point: > 50 °C
Flash point: No data available
Relative evaporation rate (butylacetate=1): No data available
Flammability (solid, gas): Not applicable
Vapor pressure: No data available
Relative vapor density at 20 °C: No data available
Relative density: No data available
Solubility: No data available
Log Pow: No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Explosive limits: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other Information
No additional information available
10. STABILITY AND REACTIVITY
Reactivity
No dangerous reactions known under normal conditions of use.
Chemical stability
Stable at ambient temperature and under normal conditions of use.
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
Conditions to avoid
None known.
Incompatible materials
None known.
Hazardous decomposition products
No hazardous decomposition products known at room temperature. On combustion, forms: carbon oxides (CO and CO2)
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity (oral) : Not classified (Based on available data, the classification criteria are not met)
Acute toxicity (dermal) : Not classified (Based on available data, the classification criteria are not met)
Acute toxicity (inhalation) : Not classified (Based on available data, the classification criteria are not met)
Acetone (67-64-1)
LD50 oral rat 5800 mg/kg
LD50 dermal rabbit > 15700 mg/kg
LC50 inhalation rat (mg/l) 50100 mg/m³ (Exposure time: 8 h)
Ethyl alcohol (64-17-5)
LD50 oral rat 7060 mg/kg
LC50 inhalation rat (mg/l) 124.7 mg/l/4h
General:
Skin corrosion/irritation: Causes skin irritation.
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity: Not classified (Based on available data, the classification criteria are not met)
Reproductive toxicity: May damage fertility or the unborn child.
Aspiration hazard: Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity – repeated exposure: Not classified (Based on available data, the classification criteria are not met)
Aspiration hazard: Not classified (Based on available data, the classification criteria are not met)
Viscosity, kinematic: No data available
Symptoms/effects: May damage fertility or the unborn child.
Symptoms/effects after inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of normal use.
Symptoms/effects after skin contact: Causes skin irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact: Causes serious eye irritation.
Symptoms/effects after ingestion: May cause irritation to the digestive tract.
Other information: Likely routes of exposure: ingestion, inhalation, skin, and eye.
12. ECOLOGICAL INFORMATION
Toxicity
Ecology - general: This material has not been tested for environmental effects.
Acute aquatic toxicity: Not classified (Based on available data, the classification criteria are not met)
Chronic aquatic toxicity: Not classified (Based on available data, the classification criteria are not met)
Acetone (67-64-1)
LC50 fish 1 4.74 - 6.33 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
LC50 fish 2 6210 - 8120 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Daphnia 1 10294 - 17704 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
EC50 Daphnia 2 12600 - 12700 mg/l (Exposure time: 48 h - Species: Daphnia magna)
ErC50 (algae) > 2800 mg/l 14days
Ethyl alcohol (64-17-5)
LC50 fish 1 12.0 - 16.0 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
LC50 fish 2 > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
LC50 other aquatic organisms 1 5012 mg/l 48 hours- daphnia
EC50 Daphnia 1 9268 - 14221 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 Daphnia 2 2 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
ErC50 (algae) 275 mg/l ErC50 (other aquatic plants) 4432 mg/l
NOEC (acute) 9.6 mg/l Daphnia magna
Persistence and degradability
No additional information available
Bioaccumulative potential
Acetone (67-64-1)
BCF fish 1 0.69
Log Pow -0.24
Ethyl alcohol (64-17-5)
Log Pow -0.32
Mobility in soil
No additional information available
Other adverse effects Additional information:
Avoid release to the environment
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials: Avoid release to the environment.
14. TRANSPORT INFORMATION
Department of Transportation (DOT)
In accordance with DOT
Transport document description: UN1993 Flammable liquids, n.o.s. (Ethyl alcohol), 3, II
UN-No.(DOT): UN1993
Proper Shipping Name (DOT): Flammable liquids, n.o.s.
Ethyl alcohol
Class (DOT): 3 - Class 3 - Flammable and combustible liquid 49 CFR
73.120
Packing group (DOT): II - Medium Danger
Hazard labels (DOT): 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx): 202
DOT Packaging Bulk (49 CFR 173.xxx): 242
DOT Special Provisions (49 CFR 172.102): IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than o or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx): 150
DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27): 5 L
DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75): 60 L
DOT Vessel Stowage Location: B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.
Emergency Response Guide (ERG) Number: 128
Other information: No supplementary information available.
Transportation of Dangerous Goods
Transport document description: UN1993 FLAMMABLE LIQUID, N.O.S. (Ethyl alcohol), 3, II
UN-No. (TDG): UN1993
Proper Shipping Name (Transportation of Dangerous Goods): FLAMMABLE LIQUID, N.O.S.
TDG Primary Hazard Classes: 3 - Class 3 - Flammable Liquids
Packing group: II - Medium Danger
TDG Special Provisions: 16 - (1) The technical name of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods must be shown, in parentheses, on the shipping document following the shipping name in accordance with clause 3.5(1)(c)(ii)(A) of Part (Documentation). The technical name must also be shown, in parentheses, on a small means of containment or on a tag following the shipping name in accordance with subsections 4.11(2) and (3) of Part 4 (Dangerous Goods Safety Marks). (2) Despite subsection (1), the technical name for the following dangerous goods is not required to be shown on a shipping document or on a small means of containment when Canadian law for domestic transport or an international convention for international transport prohibits the disclosure of the technical name: (a)UN1544, ALKALOID SALTS, SOLID, N.O.S. or ALKALOIDS, SOLID, N.O.S; ( b) UN1851, MEDICINE, LIQUID, TOXIC, N.O.S; (c)UN3140, ALKALOID SALTS, LIQUID, N.O.S. or ALKALOIDS, LIQUID, N.O.S; (d)UN3248, MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S; or (e)UN3249, MEDICINE, SOLID, TOXIC, N.O.S. An example in Canada is the “Food and Drugs Act”. (3) Despite subsection (1), the technical name for th following dangerous goods is not required to be shown on a small means of containment: (a)UN2814, INFECTIOUS SUBSTANCE, AFFECTING HUMANS; or (b)UN2900, INFECTIOUS SUBSTANCE, AFFECTING ANIMALS. SOR/2014-306,150 - An emergency response assistance plan (ERAP) is required for these dangerous goods under subsection 7.1(6) of Part 7 (Emergency Response Assistance Plan).
Explosive Limit and Limited Quantity Index: 1 L
Passenger Carrying Road Vehicle or Passenger Carrying
Railway Vehicle Index: 5 L
Transport by sea
Transport document description (IMDG): UN 1993 FLAMMABLE LIQUID, N.O.S. (Ethyl alcohol), 3, II
UN-No. (IMDG): 1993
Proper Shipping Name (IMDG): FLAMMABLE LIQUID, N.O.S.
Class (IMDG): 3 - Flammable liquids
Packing group (IMDG): II - substances presenting medium danger
Limited quantities (IMDG): 1 L
Air transport
Transport document description (IATA): UN 1993 Flammable liquid, n.o.s. (Ethyl alcohol), 3, II
UN-No. (IATA): 1993
Proper Shipping Name (IATA): Flammable liquid, n.o.s.
Class (IATA): 3 - Flammable Liquids
Packing group (IATA): II - Medium Danger
15. REGULATORY INFORMATION
US Federal Regulations
Acetone (67-64-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
CERCLA RQ: 5000lbs
2-hydroxyethyl methacrylate (868-77-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester (1565-94-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Ethyl alcohol (64-17-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Benzoic acid, 4-(dimethylamino)-, ethyl ester (10287-53-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
16. OTHER INFORMATION
HMIS RATING:
HMIS RATING:
RATINGS:
0 = Minimal
1 = Slight
2 = Hazardous
3 = Serious
4 = Severe
PREPARED BY: Jörg Erxleben
REVISION SUMMARY: First Edition.
MANUFACTURER DISCLAIMER:
To the best of our knowledge, the information contained herein is accurate. However, Harvest Dental Products, LLC does not assume any liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
FRM-SDS-21 REV 00 | Page 15 of 15
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