Harvest EasyGum Bond - Safety Data Sheet

Flammable liquids Category 2  
 Skin corrosion/irritation Category 2 
 Serious eye damage/eye irritation Category 2
 Skin sensitization, Category 1  
 Reproductive toxicity Category 1B  

  Highly flammable liquid and vapor  
 Causes skin irritation  
 Causes serious eye irritation  
   May cause an allergic skin reaction  
 May damage fertility or the unborn child 

 Hazard Pictograms (GHS US): 

Signal Ward (GHS US): 

Danger

Hazard Statements: 

Highly flammable liquid and vapor 
 Causes skin irritation  
    May cause an allergic skin reaction  
     Causes serious eye irritation  
     May damage fertility or the unborn child

Precautionary Statements (GHS US): 

Obtain special instructions before use. 

Do not handle until all safety precautions have been read and understood.  
     Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.  
     Keep container tightly closed. 
     Use explosion-proof electrical/ventilating/lighting     equipment  
     Use only non-sparking tools.  
    Avoid breathing vapors, spray. 

 Wash hands thoroughly after handling.  
    Contaminated work clothing must not be allowed     out of the workplace 
     Wear protective gloves, eye protection.  

    If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with     water/shower 
     If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 
     If exposed or concerned: Get medical advice/attention. 
    If skin irritation or rash occurs: Get medical advice/attention.  
     If eye irritation persists: Get medical advice/attention. 
     Take off contaminated clothing and wash it before reuse.  
     Wash contaminated clothing before reuse. 
   Store in a well-ventilated place. Keep cool.   

   Store locked up. 
     Dispose of contents/container to hazardous or     special waste collection point, in accordance with     local, regional, national and/or international     regulation

Name

CAS No

Percentage

GHS-US Classification 

2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester  
 

(CAS-No.) 1565-94-2   

15 - 40  
 

Skin Irrit. 2, H315  

Eye Irrit. 2A, H319  

Skin Sens. 1, H317 

Ethyl alcohol 

(CAS-No.) 64-17-5  
 

15 – 40   

Flam. Liq. 2, H225  

Eye Irrit. 2A, H319  

Bis[2-[(2-methyl-1-oxoallyl)oxy]ethyl] dihydrogen benzene-1,2,4,5-tetracarboxylate   

(CAS-No.) 51156-91-3  
 

10 - 30  
 

Skin Irrit. 2, H315  

Eye Irrit. 2A, H319  

STOT SE 3, H335  

Comb. Dust  

2-hydroxyethyl methacrylate  

(CAS-No.) 868-77-9  

10 - 30   

Skin Irrit. 2, H315  

Eye Irrit. 2, H319  

Skin Sens. 1, H317  

10- Methacryloyloxydecyl dihydrogen phosphate (10-MDP)   

(CAS-No.) 85590-00-7   

7 - 13   

Eye Irrit. 2, H319  

Skin Sens. 1, H317  

Acetone   

(CAS-No.) 67-64-1   

1 - 5   

Flam. Liq. 2, H225  

Eye Irrit. 2, H319  

STOT SE 3, H336   

Benzoic acid, 4-(dimethylamino)-, ethyl ester  

(CAS-No.) 10287-53-3  

0.5 – 1.5

Repr. 1B, H360

First-aid measures after inhalation: 

Remove person to fresh air and keep comfortable for breathing.  
     Give artificial respiration if necessary. If you feel unwell, seek medical advice.  

First-aid measures after skin contact:

Immediately, remove all contaminated clothing. Rinse immediately with plenty of water for 15 minutes. Seek medical advice if skin irritation persists

First-aid measures after eye contact:

Remove contact lenses, if present and easy to do.Continue rinsing.  
     Rinse immediately with plenty of water for 15 minutes.   
     If eye irritation persists: Seek medical advice and attention. 

First-aid measures after ingestion: 

Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention

Symptoms/effects:  
 Symptoms/effects after inhalation: 
 
 Symptoms/effects after skin contact: 
 Symptoms/effects after eye contact: 
 Symptoms/effects after ingestion: 

  May damage fertility or the unborn child.  
 Not expected to present a significant inhalation hazard under anticipated conditions of normal use.  
   Causes skin irritation. May cause an allergic skin reaction.  
 Causes serious eye irritation.  
 May cause irritation to the digestive tract. 

Suitable Extinguishing media:  

Water spray, Foam, dry powder, carbon dioxide. Sand.

Unsuitable Extinguishing media:

Do not use a heavy water stream 

Fire hazard: 

On combustion, forms: carbon oxides (CO and CO2).

Explosion hazard:  

 May form flammable vapor-air mixture. Vapors may travel long distances along the ground before igniting/flashing back to vapor source.   

Reactivity in case of fire: 

Stable under normal conditions.

Firefighting instructions: 

 Use water spray or fog for cooling exposed containers.  
 Exercise caution when fighting any chemical fire. Prevent 
 firefighting water from entering the environment.  

 Protective equipment for firefighters:

Do not enter fire area without proper protective equipment,     including respiratory protection. 

Protective equipment for firefighters: 

 Do not enter fire area without proper protective equipment, including respiratory protection

General measures: 

Keep away from open flames, hot surfaces, and sources of ignition.

Protective equipment:  

 Use personal protective equipment as required. For further  information refer to section 8: "Exposure controls/personal protection"

 Emergency procedures: 

Evacuate unnecessary personnel. 

Protective equipment:

Wear recommended personal protective equipment. For further information refer to Section 8: "Exposure controls/personal protection".

Emergency procedures:

Ventilate area.

Methods for cleaning up: 

Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials

Other information: 

Dispose of materials or solid residues at an authorized site

Additional hazards when processed:

 Handle empty containers with care as residual vapors are flammable.

Precautions for safe handling:

Ensure good ventilation of the workstation. Avoid contact with eyes. Wear personal protective equipment. Avoid breathing vapors, mist.

Hygiene measures: 

Do not eat, drink, or smoke when using this product. Always wash hands after handling the product. Wash contaminated clothing before reuse. Handle in accordance with good industrial hygiene and safety practice.

Technical measures: 

Use explosion-proof electrical/ventilating/lighting equipment. Keep away from open flames, hot surfaces, and sources of ignition. 

Storage conditions: 

Store in a well-ventilated place. Keep cool. 

Incompatible materials: 

None known. 

Ingredients

Value 

Bis[2-[(2-methyl-1-oxoallyl)oxy]ethyl] dihydrogen benzene-1,2,4,5-tetracarboxylate

Not applicable 

Acetone

Local Name 

Acetone  

ACGIH TWA  

250 ppm 

ACGIH STEL 

500 ppm 

ACGIH Remark 

TLV® Basis: URT & eye irr; CNS impair. Notations: A4 (Not classifiable as a Human Carcinogen); BEI 

BEI 

25 mg/l Parameter: Acetone - Medium: urine - Sampling time: End of shift - Notations: Ns 

Regulatory Reference 

ACGIH 2019 

OSHA PEL (TWA) 

2400 mg/m³ 

OSHA PEL (TWA) 

1000 ppm 

Regulatory reference 

OSHA Annotated Table Z-1 

NIOSH REL (TWA) 

590 mg/m³ 

NIOSH REL (TWA) 

250 ppm 

2-hydroxyethyl methacrylate

Not applicable 

2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis[4,1- phenyleneoxy(2-hydroxy-3,1-propanediyl)] ester 

Not applicable 

10- Methacryloyloxydecyl dihydrogen phosphate (10-MDP) 

Not applicable 

Ethyl alcohol 

Local Name 

Ethanol 

ACGIH STEL 

1000 ppm 

ACGIH Remark 

TLV® Basis: URT irr. Notations: A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans) 

Regulatory Reference 

ACGIH 2019 

OSHA PEL (TWA) 

1900 mg/m³ 

OSHA PEL (TWA) 

1000 ppm 

Regulatory reference 

OSHA Annotated Table Z-1 

US IDLH 

3300 ppm (10% LEL) 

NIOSH REL (TWA) 

1900 mg/m³ 

NIOSH REL (TWA) 

1000 ppm 

Benzoic acid, 4-(dimethylamino)-, ethyl ester 

Not applicable 

Appropriate Engineering: 

Ensure good ventilation of the workstation. Emergency eye-wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. 

Environmental Exposure Controls: 

Avoid release to the environment. 

LD50 oral rat  

5800 mg/kg  

LD50 dermal rabbit 

> 15700 mg/kg  

LC50 inhalation rat (mg/l)  

 50100 mg/m³ (Exposure time: 8 h) 

LD50 oral rat  

7060mg/kg

LC50 inhalation rat (mg/l)  

  124.7 mg/l/4h 

Skin corrosion/irritation:  

Causes skin irritation. 

Serious eye damage/irritation:  

Causes serious eye irritation. 

Respiratory or skin sensitization 

May cause an allergic skin reaction. 

Germ cell mutagenicity:  

Not classified (Based on available data, the classification criteria are not met)

Carcinogenicity: 

Not classified (Based on available data, the classification criteria are not met)

Reproductive toxicity: 

May damage fertility or the unborn child. 

Aspiration hazard: 

Not classified (Based on available data, the classification criteria are not met)

Specific target organ toxicity – repeated exposure: 

Not classified (Based on available data, the classification criteria are not met) 

Aspiration hazard: 

Not classified (Based on available data, the classification criteria are not met)

Viscosity, kinematic: 

No data available 

Symptoms/effects:  

May damage fertility or the unborn child. 

Symptoms/effects after inhalation:

Not expected to present a significant inhalation hazard under anticipated conditions of normal use. 

Symptoms/effects after skin contact: 

Causes skin irritation. May cause an allergic skin reaction 

Symptoms/effects after eye contact: 

Causes serious eye irritation. 

Symptoms/effects after ingestion: 

May cause irritation to the digestive tract. 

Other information: 

Likely routes of exposure: ingestion, inhalation, skin, and eye. 

LC50 fish 1 

 4.74 - 6.33 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) 

LC50 fish 2 

 6210 - 8120 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 

EC50 Daphnia 1 

10294 - 17704 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 

EC50 Daphnia 2 

12600 - 12700 mg/l (Exposure time: 48 h - Species: Daphnia magna) 

ErC50 (algae) 

> 2800 mg/l 14days

LC50 fish 1 

 12.0 - 16.0 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) 

LC50 fish 2 

 > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])  

LC50 other aquatic organisms  1

 5012 mg/l 48 hours- daphnia  

EC50 Daphnia 1  

 9268 - 14221 mg/l (Exposure time: 48 h - Species: Daphnia magna) 

EC50 Daphnia 2 

 2 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])  

ErC50 (algae) 

 275 mg/l ErC50 (other aquatic plants) 4432 mg/l 

NOEC (acute)  

  9.6 mg/l Daphnia magna 

Classification code (ADR): 

F1 

Special provisions (ADR): 

274, 601, 640D 

Limited quantities (ADR): 

1l 

Excepted quantities (ADR): 

E2 

Packing instructions (ADR): 

P001, IBC02, R001
 

Mixed packing provisions (ADR): 

MP19 
 

Portable tank and bulk container instructions (ADR): 

T7
 

Portable tank and bulk container special provisions (ADR): 

TP1, TP8, TP28 

Tank code (ADR): 

LGBF 

Vehicle for tank carriage:
 

FL

Transport category (ADR): 

2

Special provisions for carriage - Operation (ADR): 

S2, S20 

Hazard identification number (Kemler No.): 

33

Orange Plates: 

Tunnel restriction code (ADR): 

D/E 

EAC code: 

•3YE
 

Excepted quantities (IMDG): 

E2

Excepted quantities (IATA): 

E2

Classification code (ADN) 

F1

Special provisions (ADN):

274, 601, 640D

Limited quantities (ADN):

1 L

Excepted quantities (ADN): 

E2

Carriage permitted (ADN):

T

Equipment required (ADN):

PP, EX, A
 

Ventilation (ADN):

VE01

Number of blue cones/lights (ADN): 

1

Classification code (RID): 

F1

Special provisions (RID):

274, 601, 640D

Limited quantities (RID):

1 L

Excepted quantities (RID):
 

E2

Packing instructions (RID):

P001, IBC02, R001

Mixed packing provisions (RID): 

MP19

Portable tank and bulk container instructions (RID):

T7

Portable tank and bulk container special provisions (RID): 

TP1, TP8, TP28
 

Tank codes for RID tanks (RID):

LGBF

Transport category (RID):

2

Colis express (express parcels) (RID):
 

CE7